Initial Bubble Conditions
The DT gas bubble contains 3 mg of DT. Taking D–T molecular mass ≈5 g/mol (deuterium+tritium), the moles of gas are
n = (3×10^{−3}g)(mol/5g) = 6.0×10^{−4} mol.
At 750 K and 1 atm, we use the ideal-gas law (PV=nRT) to find the initial volume:
V_0=nRT_0/P_0
= (6.0×10^{−4} mol)(8.314 J/mol·K)(750 K)/(1.013×10^5 Pa)
≈ 3.69×10^{−5} m^3
Assuming a spherical bubble, the initial radius is
R_0=(3V_0/4π)^{1/3}≈(3×3.69×10^{−5}/4π)^{1/3}≈0.0207 m (2.07 cm).
Adiabatic Compression
The external pressure jumps to P_f=10,000 atm (≈ 1.013\times10^9 Pa). We assume the compression is fast and adiabatic (Q=0). For an ideal gas undergoing a (quasi-static) adiabatic process, P V^\gamma= constant, where \gamma is the heat-capacity ratio. For diatomic DT at high temperature (rotations excited, vibrations partially excited) we take \gamma\approx1.4. Thus
P_0V_0^γ=P_fV_f^γ ⟹ V_f=V_0(P_0/P_f)^{1/γ}.
Substituting P_0=1.013\times10^5 Pa, P_f=1.013\times10^9 Pa, and \gamma=1.4,
V_f ≈ 5.14×10^{−8}m^3.
The final bubble radius is R_f ≈ 2.3×10^{−3} m (2.3 mm).
Final Temperature
Adiabatic compression also raises the gas temperature. For an ideal gas, one can combine PV=nRT and P V^\gamma= const to get T_f/T_0=(V_0/V_f)^{γ−1} = (P_f/P_0)^{(γ−1)/γ}.
Using \gamma=1.4, T_0=750 K, P_f/P_0=10^4, we find
T_f=750×(10^4)^{0.4/1.4}
≈ 10,500 K.
Time to Maximum Compression
For a spherical gas bubble collapsing in an incompressible liquid under a sudden pressure jump, the Rayleigh collapse time gives a good first-order estimate:
T_c \approx 0.915 \cdot R_0 \sqrt{\frac{\rho_L}{P_\infty}}
Where:
- T_c = collapse time
- R_0 = initial bubble radius
- ρ_L = liquid density
- P_∞ = external overpressure driving the collapse
Example: DT Bubble in Molten FLiBe
- R_0 = 2.07 cm
- ρ_L = 2000 kg/m³ (approx. for FLiBe)
- P_∞ = 10,000 atm ≈ 1.013×10^9 Pa
Plugging in:
T_c \approx 0.915 \cdot 0.0207 \cdot \sqrt{\frac{2000}{1.013 \times 10^9}} \approx 2.6 \times 10^{-5} \text{ s}
This 26 microseconds collapse time is consistent with a 50 μs pressure pulse duration. Thus the bubble should reach minimum radius before the pulse of pressure vacates the area.
Summary: The 3 mg DT bubble (initially at 750 K, 1 atm) has initial radius R_0\approx2.07 cm. Under a 10 000 atm adiabatic compression, the final radius is R_f\approx2.28 mm, the final temperature T_f\approx1.0\times10^4 K.