Nice instincts, Thomas. Let me put some numbers on the doubt.
Let’s make the assumptions explicit and as friendly as possible to the scheme:
- Initial gas: DT in the bubble, treated as an ideal gas
- Molar mass: M \approx 5\ \text{g/mol} = 5\times 10^{-3}\ \text{kg/mol}
- Mass of DT: m = 1\ \text{mg} = 1\times 10^{-6}\ \text{kg}
- Initial pressure: P_1 = 1\ \text{bar} = 1\times 10^{5}\ \text{Pa}
- Initial temperature: T_1 = 750\ \text{K}
- Peak acoustic pressure at collapse: P_2 = 5\ \text{kbar} = 5\times 10^{8}\ \text{Pa}
- Process: adiabatic compression of the bubble
- Heat capacity ratio: I’ll be generous and take \gamma = 5/3 (more heating than a diatomic \gamma = 1.4)
Step 1: Amount of DT and initial bubble size
Moles of DT:
n = \frac{m}{M} = \frac{1\times 10^{-6}}{5\times 10^{-3}} = 2\times 10^{-4}\ \text{mol}
Initial volume from ideal gas law:
P_1 V_1 = n R T_1
V_1 = \frac{n R T_1}{P_1}
= \frac{(2\times 10^{-4})(8.314)(750)}{1\times 10^{5}}
nRT_1 \approx 2\times 10^{-4} \times 6235.5 \approx 1.25
V_1 \approx \frac{1.25}{1\times 10^{5}} \approx 1.25\times 10^{-5}\ \text{m}^3
Initial radius assuming a sphere:
V_1 = \frac{4}{3}\pi r_1^3 \quad\Rightarrow\quad
r_1 = \left(\frac{3V_1}{4\pi}\right)^{1/3}
\frac{3V_1}{4\pi} \approx \frac{3\times 1.25\times 10^{-5}}{12.566} \approx 3.0\times 10^{-6}
r_1 \approx (3.0\times 10^{-6})^{1/3} \approx 1.4\times 10^{-2}\ \text{m} \approx 1.4\ \text{cm}
So we’re talking about a ~1.4 cm radius DT bubble at 1 bar, 750 K, containing 2\times 10^{-4} mol of DT.
Total number of molecules:
N \approx n N_A \approx (2\times 10^{-4})(6.022\times 10^{23}) \approx 1.2\times 10^{20}\ \text{molecules}
Step 2: Adiabatic compression to 5 kbar
For an adiabatic process:
P V^\gamma = \text{const}, \quad T V^{\gamma-1} = \text{const}
Volume ratio:
\frac{V_2}{V_1} = \left(\frac{P_1}{P_2}\right)^{1/\gamma}
= \left(\frac{1\times 10^{5}}{5\times 10^{8}}\right)^{1/(5/3)}
= (2\times 10^{-4})^{0.6}
More directly:
\frac{P_2}{P_1} = 5000
\frac{V_2}{V_1} = \left(\frac{P_1}{P_2}\right)^{1/\gamma}
= 5000^{-0.6}
5000^{0.6} \approx e^{0.6 \ln 5000} \approx e^{0.6\times 8.517} \approx e^{5.11} \approx 165
\Rightarrow \frac{V_2}{V_1} \approx \frac{1}{165}
So:
V_2 \approx \frac{V_1}{165} \approx \frac{1.25\times 10^{-5}}{165} \approx 7.6\times 10^{-8}\ \text{m}^3
Final radius:
r_2 = r_1 \left(\frac{V_2}{V_1}\right)^{1/3}
= r_1 \left(\frac{1}{165}\right)^{1/3}
165^{1/3} \approx 5.5
r_2 \approx \frac{1.4\ \text{cm}}{5.5} \approx 0.26\ \text{cm} = 2.6\ \text{mm}
So even at 5 kbar, the bubble only shrinks from ~1.4 cm radius to ~2.6 mm radius under this adiabatic model.
Final temperature:
T_2 = T_1 \left(\frac{P_2}{P_1}\right)^{(\gamma-1)/\gamma}
= 750 \times 5000^{(2/5)}
5000^{0.4} \approx e^{0.4\times 8.517} \approx e^{3.41} \approx 30
T_2 \approx 750 \times 30 \approx 2.3\times 10^{4}\ \text{K}
If we instead used a more conservative diatomic \gamma = 1.4:
T_2 = 750 \times 5000^{0.2857} \approx 750 \times 11.4 \approx 8.6\times 10^{3}\ \text{K}
So even with optimistic \gamma = 5/3, we’re in the few \times 10^{4}\ \text{K} range, not millions of kelvin.
Step 3: Time to reach stagnation
For an order-of-magnitude collapse time, assume the bubble wall moves inward at roughly the speed of sound in the surrounding liquid (say FLiBe or something similarly dense):
- Speed of sound in liquid: take c \sim 2000\ \text{m/s} as a ballpark
- Distance traveled by the wall: from r_1 \approx 1.4\ \text{cm} to r_2 \approx 0.26\ \text{cm}, so \Delta r \approx 1.1\ \text{cm} = 1.1\times 10^{-2}\ \text{m}
Then:
t_{\text{collapse}} \sim \frac{\Delta r}{c} \approx \frac{1.1\times 10^{-2}}{2000} \approx 5.5\times 10^{-6}\ \text{s}
So a few microseconds from initial state to stagnation is a reasonable estimate.
Back to your doubt
So, under assumptions that are actually quite generous to the concept:
- Initial bubble: r_1 \sim 1.4\ \text{cm}, T_1 = 750\ \text{K}, P_1 = 1\ \text{bar}, n = 2\times 10^{-4}\ \text{mol}
- Peak compression: P_2 = 5\ \text{kbar}
- Adiabatic heating: T_2 \sim 2\times 10^{4}\ \text{K} (optimistic)
- Final radius: r_2 \sim 2.6\ \text{mm}
- Collapse time: \mathcal{O}(5\ \mu\text{s})
That’s hot and fast by everyday standards, but it’s still a long way from the kind of extreme temperatures and intensities you’d want if the sonoluminescent flash is supposed to act as a robust, high-gain optical trigger for a lasing cascade that then neatly refocuses back onto the bubble.
So yes, Thomas—given these starting conditions and a 5 kbar acoustic drive, your skepticism about “sufficient temperature for an intense enough pulse” looks very well founded.